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Deshwitat: Yes, yes. There are various positions still open,
Captain of Second Division
Lieutenant of Second Division
Lieutenant of Third Division
Captain of Fourth Division
Lieutenant of Fourth Division
Captain of Fifth Division
Lieutenant of Fifth Division
Captain of Sixth Division
Lieutenant of Sixth Division
Captain of Seventh Division
Lieutenant of Seventh Division
Captain of Eighth Division
Lieutenant of Eighth Division
Captain of Ninth Division
Lieutenant of Ninth Division
Lieutenant of Tenth Division
Captain of Twelfth Division
Lieutenant of Twelfth Division
Espada #2
Espada #5
Espada #6
Espada #7
Espada #8
Espada #9
Espada #0
As far as I know, those are the available main positions.